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Because we hold federal records and the government officially started in 1776, we would not have these records. The Delaware Historical Society has a guide for researching Delaware genealogy. Also, try the Delaware State Archives.
Ancestry.com has quite a bit of pre-1776 Delaware records. Ancestry can be accessed for free at all National Archives research facilities and many public libraries.
We have additional information about researching naturalization on our website.
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Since you are researching New Castle, Delaware I thought this might interest you.
Ireland Genealogy • FamilySearch familysearch.org is a free website, you just need to register to use.