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Generally, personal wills are not maintained by the federal government and are not in the custody of The National Archives and Records Administration. The probate of a will is usually overseen by state or municipal courts. You may find some useful information on NARA's "Resources for Genealogists" page here: https://www.archives.gov/research/genealogy/start-research/nara-resources
Because the will was written before the creation of the Constitution, the local courts may not have possession of the will. You may wish to try the Virginia State Archives or the Virginia Historical Society Library.
We hope this information is helpful in your research.
The National Archives and Records Administration
A lot of the Caroline County VA courthouse records were destroyed during the civil war. The following is from the Caroline Co VA familysearch wiki:
1864. Most antebellum probate prior to 1853, land records prior to 1836, and loose papers were lost during the American Civil War, 1861-1865 and, of those that are extant, many of those are scattered among the Virginia State Archives, the Caroline County Circuit Court, and the Circuit Court for the City of Fredericksburg. Postbellum land and probate records can be presumed to be housed at the Caroline County Courthouse.